Hydrogen & Energy  
Hydrogen and Hydrides
Structure and Dynamics
Stability and Kinetics
Electrochemistry
Theoretical Modelling
Hydrogen Safety
Instruments
Spectroscopy
Materials development

Hydrogen Safety and Instruments

Hydrogen storage in metal and complex hydrides is the phase transformation of hydrogen from gas to solid at a temperature above the critical point of hydrogen. Two factors have to be considered for the construction of a solid hydrogen storage system, i.e. the volume expansion upon hydrogen absorption (approx. 20Vol%) and the heat effect due to the entropy change of the hydrogen gas (S0 = 130 J K-1 mol-1). Furthermore, most hydrides decompose into a fine powder (grain size 10 - 100 mm) upon hydrogen absorption. The density of the powder material  is  approximately 70% of the density of the bulk material.

Projects

  • Construction of various size hydrogen storage systems for demonstration projects.
  • Construction of a new pcT-analyzer for hydrides (Activation, pcT, BET, Kinetics)
  • Investigation of the safety parameters of new hydride materials.
  • Investigation of the safety parameters of hydrogen storage systems.
  • Development of the safety standards for the operation of hydrogen storage systems.

contact:

Dr. Michael Bielmann, michael.bielmann@empa.ch

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