Publications 2023

Kravchyk, K. V.; Kovalenko, M. V. On achievable gravimetric and volumetric energy densities of Al dual-ion batteries. ACS Energy Lett. 2023, 8 (2), 1266-1269. https://doi.org/10.1021/acsenergylett.2c02908
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Klimpel, M.; Zhang, H.; Kovalenko, M. V.; Kravchyk, K. V. Standardizing critical current density measurements in lithium garnets. Communications Chem. 2023, 6 (1), 192 (3 pp.). https://doi.org/10.1038/s42004-023-01002-4
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Welty, C.; Taylor, E. E.; Posey, S.; Vailati, P.; Kravchyk, K. V.; Kovalenko, M. V.; Stadie, N. P. Methodological studies of the mechanism of anion insertion in nanometer-sized carbon micropores. ChemSusChem 2023, 16 (4), e202201847 (11 pp.). https://doi.org/10.1002/cssc.202201847
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Ren, A.; Wang, H.; Dai, L.; Xia, J.; Bai, X.; Butler-Caddle, E.; Smith, J. A.; Lai, H.; Ye, J.; Li, X.; et al. High-bandwidth perovskite photonic sources on silicon. Nat. Photonics 2023, 17, 798-805. https://doi.org/10.1038/s41566-023-01242-9
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Priebe, A.; Aribia, A.; Sastre, J.; Romanyuk, Y. E.; Michler, J. 3D high-resolution chemical characterization of sputtered Li-rich NMC811 thin films using TOF-SIMS. Anal. Chem. 2023, 95 (2), 1074-1084. https://doi.org/10.1021/acs.analchem.2c03780
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Boumenou, C. K.; Phirke, H.; Rommelfangen, J.; Audinot, J. N.; Nishiwaki, S.; Wirtz, T.; Carron, R.; Redinger, A. Nanoscale surface analysis reveals origins of enhanced interface passivation in RbF post deposition treated CIGSe solar cells. Adv. Funct. Mater. 2023, 33 (30), 2300590 (15 pp.). https://doi.org/10.1002/adfm.202300590
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Siegrist, S.; Nandi, P.; Kothandaraman, R. K.; Abdessalem, A.; Tiwari, A. N.; Fu, F. Understanding coating thickness and uniformity of blade-coated SnO2 electron transport layer for scalable perovskite solar cells. Sol. RRL 2023, 7 (14), 2300273 (7 pp.). https://doi.org/10.1002/solr.202300273
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Shrivastava, M.; Krieg, F.; Kovalenko, M. V.; Adarsh, K. V. Photon-dressed biexciton-mediated anomalous optical Stark effect in CsPbBr3 nanocrystals. Surf. Interface Anal. 2023, 55 (6-7), 501-506. https://doi.org/10.1002/sia.7153
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Limantoro, C.; Das, T.; He, M.; Dirin, D.; Manos, J.; Kovalenko, M. V.; Chrzanowski, W. Synthesis of antimicrobial gallium nanoparticles using the hot injection method. ACS Mater. Au 2023, 3 (4), 310-320. https://doi.org/10.1021/acsmaterialsau.2c00078
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Kurisinkal Pious, J.; Zwirner, Y.; Lai, H.; Olthof, S.; Jeangros, Q.; Gilshtein, E.; Kothandaraman, R. K.; Artuk, K.; Wechsler, P.; Chen, C.; et al. Revealing the role of tin fluoride additive in narrow bandgap Pb-Sn perovskites for highly efficient flexible all-perovskite tandem cells. ACS Appl. Mater. Interfaces 2023, 15 (7), 10151-10157. https://doi.org/10.1021/acsami.2c19124
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Grisard, S.; Trifonov, A. V.; Solovev, I. A.; Yakovlev, D. R.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M.; Akimov, I. A. Long-lived exciton coherence in mixed-halide perovskite crystals. Nano Lett. 2023, 23 (16), 7397-7403. https://doi.org/10.1021/acs.nanolett.3c01817
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Häusermann, D.; Bodry, S.; Wiesemüller, F.; Miriyev, A.; Siegrist, S.; Fu, F.; Gaan, S.; Koebel, M. M.; Malfait, W. J.; Zhao, S.; et al. FireDrone: multi-environment thermally agnostic aerial robot. Adv. Intell. Syst. 2023, 5 (9), 2300101 (11 pp.). https://doi.org/10.1002/aisy.202300101
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Warby, J.; Shah, S.; Thiesbrummel, J.; Gutierrez-Partida, E.; Lai, H.; Alebachew, B.; Grischek, M.; Yang, F.; Lang, F.; Albrecht, S.; et al. Mismatch of quasi–fermi level splitting and Voc in perovskite solar cells. Adv. Energy Mater. 2023, 13 (48), 2303135 (12 pp.). https://doi.org/10.1002/aenm.202303135
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Nette, J.; Montanarella, F.; Zhu, C.; Sekh, T. V.; Boehme, S. C.; Bodnarchuk, M. I.; Rainò, G.; Howes, P. D.; Kovalenko, M. V.; deMello, A. J. Microfluidic synthesis of monodisperse and size-tunable CsPbBr3 supraparticles. Chem. Commun. 2023, 59, 3554 (4 pp.). https://doi.org/10.1039/d3cc00093a
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Dirin, D. N.; Vivani, A.; Zacharias, M.; Sekh, T. V.; Cherniukh, I.; Yakunin, S.; Bertolotti, F.; Aebli, M.; Schaller, R. D.; Wieczorek, A.; et al. Intrinsic formamidinium tin iodide nanocrystals by suppressing the Sn(IV) impurities. Nano Lett. 2023, 23, 1914-1923. https://doi.org/10.1021/acs.nanolett.2c04927
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Kara, G.; Bolat, S.; Sharma, K.; Grotevent, M. J.; Dirin, D. N.; Bachmann, D.; Furrer, R.; Boesel, L. F.; Romanyuk, Y. E.; Rossi, R. M.; et al. Conformal integration of an inkjet‐printed PbS QDs‐graphene IR photodetector on a polymer optical fiber. Adv. Mater. Technol. 2023, 8 (9), 2201922 (11 pp.). https://doi.org/10.1002/admt.202201922
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Wieczorek, A.; Lai, H.; Pious, J.; Fu, F.; Siol, S. Resolving oxidation states and X–site composition of Sn perovskites through Auger parameter analysis in XPS. Adv. Mater. Interfaces 2023, 10 (7), 2201828 (7 pp.). https://doi.org/10.1002/admi.202201828
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Moser, S.; Aribia, A.; Scaffidi, R.; Gilshtein, E.; Brammertz, G.; Vermang, B.; Tiwari, A. N.; Carron, R. Controlled li alloying by postsynthesis electrochemical treatment of Cu2ZnSn(S, Se)4 absorbers for solar cells. ACS Appl. Energy Mater. 2023, 6 (24), 12515-12525. https://doi.org/10.1021/acsaem.3c02483
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Zhang, H.; Okur, F.; Cancellieri, C.; Jeurgens, L. P. H.; Parrilli, A.; Karabay, D. T.; Nesvadba, M.; Hwang, S.; Neels, A.; Kovalenko, M. V.; et al. Bilayer dense‐porous Li7La3Zr2O12 membranes for high‐performance Li‐garnet solid‐state batteries. Adv. Sci. 2023, 10 (8), 2205821 (10 pp.). https://doi.org/10.1002/advs.202205821
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Baumgärtner, J. F.; Wörle, M.; Guntlin, C. P.; Krumeich, F.; Siegrist, S.; Vogt, V.; Stoian, D. C.; Chernyshov, D.; van Beek, W.; Kravchyk, K. V.; et al. Pyrochlore‐type iron hydroxy fluorides as low‐cost lithium‐ion cathode materials for stationary energy storage. Adv. Mater. 2023, 35 (49), 2304158 (11 pp.). https://doi.org/10.1002/adma.202304158
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Zhao, W.; Wang, K.; Dubey, R.; Ren, F.; Brack, E.; Becker, M.; Grissa, R.; Seidl, L.; Pagani, F.; Egorov, K.; et al. Extending the high-voltage operation of graphite/NCM811 cells by constructing a robust electrode/electrolyte interphase layer. Mater. Today Energy 2023, 34, 101301 (11 pp.). https://doi.org/10.1016/j.mtener.2023.101301
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Carwithen, B. P.; Hopper, T. R.; Ge, Z.; Mondal, N.; Wang, T.; Mazlumian, R.; Zheng, X.; Krieg, F.; Montanarella, F.; Nedelcu, G.; et al. Confinement and exciton binding energy effects on hot carrier cooling in lead halide perovskite nanomaterials. ACS Nano 2023, 17 (7), 6638-6648. https://doi.org/10.1021/acsnano.2c12373
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Zhu, C.; Nguyen, T.; Boehme, S. C.; Moskalenko, A.; Dirin, D. N.; Bodnarchuk, M. I.; Katan, C.; Even, J.; Rainò, G.; Kovalenko, M. V. Many-body correlations and exciton complexes in CsPbBr3 quantum dots. Adv. Mater. 2023, 35 (9), 2208354 (9 pp.). https://doi.org/10.1002/adma.202208354
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Krause, M.; Yang, S. C.; Moser, S.; Nishiwaki, S.; Tiwari, A. N.; Carron, R. Silver-alloyed low-bandgap CuInSe2 solar cells for tandem applications. Sol. RRL 2023, 7 (9), 2201122 (10 pp.). https://doi.org/10.1002/solr.202201122
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Weiss, T. P.; Ramírez, O.; Paetel, S.; Witte, W.; Nishinaga, J.; Feurer, T.; Siebentritt, S. Metastable defects decrease the fill factor of solar cells. Phys. Rev. App. 2023, 19 (2), 024052 (23 pp.). https://doi.org/10.1103/PhysRevApplied.19.024052
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Harkort, C.; Kudlacik, D.; Kopteva, N. E.; Yakovlev, D. R.; Karzel, M.; Kirstein, E.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. Spin-flip raman scattering on electrons and holes in two-dimensional (PEA)2PbI4 perovskites. Small 2023, 19 (32), 2300988 (10 pp.). https://doi.org/10.1002/smll.202300988
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Zhang, H.; Paggiaro, G.; Okur, F.; Huwiler, J.; Cancellieri, C.; Jeurgens, L. P. H.; Chernyshov, D.; Van Beek, W.; Kovalenko, M. V.; Kravchyk, K. V. On high-temperature thermal cleaning of Li7La3Zr2O12 solid-state electrolytes. ACS Appl. Energy Mater. 2023, 6 (13), 6972-6980. https://doi.org/10.1021/acsaem.3c00459
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Zhang, H.; Dubey, R.; Inniger, M.; Okur, F.; Wullich, R.; Parrilli, A.; Karabay, D. T.; Neels, A.; Kravchyk, K. V.; Kovalenko, M. V. Ultrafast-sintered self-standing LLZO membranes for high energy density lithium-garnet solid-state batteries. Cell Rep. Phys. Sci. 2023, 4 (7), 101473 (15 pp.). https://doi.org/10.1016/j.xcrp.2023.101473
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Kumaar, D.; Can, M.; Portner, K.; Weigand, H.; Yarema, O.; Wintersteller, S.; Schenk, F.; Boskovic, D.; Pharizat, N.; Meinert, R.; et al. Colloidal ternary telluride quantum dots for tunable phase change optics in the visible and near-infrared. ACS Nano 2023, 17 (7), 6985-6997. https://doi.org/10.1021/acsnano.3c01187
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Kirstein, E.; Smirnov, D. S.; Zhukov, E. A.; Yakovlev, D. R.; Kopteva, N. E.; Dirin, D. N.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. The squeezed dark nuclear spin state in lead halide perovskites. Nat. Commun. 2023, 14 (1), 6683 (8 pp.). https://doi.org/10.1038/s41467-023-42265-8
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Aebli, M.; Kaul, C. J.; Yazdani, N.; Krieg, F.; Bernasconi, C.; Guggisberg, D.; Marczak, M.; Morad, V.; Piveteau, L.; Bodnarchuk, M. I.; et al. Disorder and halide distributions in cesium lead halide nanocrystals as seen by colloidal 133Cs nuclear magnetic resonance spectroscopy. Chem. Mater. 2023, 36 (6), 2599-3054. https://doi.org/10.1021/acs.chemmater.3c02901
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Milanese, S.; Morello, G.; De Giorgi, M. L.; Cretì, A.; Andrusiv, H.; Bodnarchuk, M. I.; Qualtieri, A.; Lomascolo, M.; Kovalenko, M. V.; Anni, M. Air-sensitive amplified spontaneous emission in lecithin-capped CsPbBr3 nanocrystals thin films. Mater. Today Phys. 2023, 35, 101098 (8 pp.). https://doi.org/10.1016/j.mtphys.2023.101098
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Seiler, H.; Zahn, D.; Taylor, V. C. A.; Bodnarchuk, M. I.; Windsor, Y. W.; Kovalenko, M. V.; Ernstorfer, R. Direct observation of ultrafast lattice distortions during exciton-polaron formation in lead halide perovskite nanocrystals. ACS Nano 2023, 17 (3), 1979-1988. https://doi.org/10.1021/acsnano.2c06727
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He, R.; Wang, W.; Yi, Z.; Lang, F.; Chen, C.; Luo, J.; Zhu, J.; Thiesbrummel, J.; Shah, S.; Wei, K.; et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 2023, 618 (7963), 80-86. https://doi.org/10.1038/s41586-023-05992-y
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Futscher, M. H.; Brinkman, L.; Müller, A.; Casella, J.; Aribia, A.; Romanyuk, Y. E. Monolithically-stacked thin-film solid-state batteries. Communications Chem. 2023, 6 (1), 110 (7 pp.). https://doi.org/10.1038/s42004-023-00901-w
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Tan, H. Q.; Liang, H.; Krause, M.; Zhao, X.; Kothandaraman, R.; Carron, R.; Tiwari, A. N.; Fu, F.; Birgersson, E.; Hou, Y.; et al. Accounting for fabrication variability in transparent perovskite solar cells for four-terminal tandem applications. Sol. RRL 2023, 7 (18), 2300339 (13 pp.). https://doi.org/10.1002/solr.202300339
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Müller, A.; Okur, F.; Aribia, A.; Osenciat, N.; Vaz, C. A. F.; Siller, V.; El Kazzi, M.; Gilshtein, E.; Futscher, M. H.; Kravchyk, K. V.; et al. Benchmarking the performance of lithiated metal oxide interlayers at the LiCoO2|LLZO interface. Mater. Adv. 2023, 4 (9), 2138-2146. https://doi.org/10.1039/d3ma00155e
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Luo, J.; He, R.; Lai, H.; Chen, C.; Zhu, J.; Xu, Y.; Yao, F.; Ma, T.; Luo, Y.; Yi, Z.; et al. Improved carrier management via a multifunctional modifier for high-quality low-bandgap Sn–Pb perovskites and rfficient sll-perovskite tandem solar cells. Adv. Mater. 2023, 35 (22), 2300352 (11 pp.). https://doi.org/10.1002/adma.202300352
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Yang, S. C.; Lin, T. Y.; Ochoa, M.; Lai, H.; Kothandaraman, R.; Fu, F.; Tiwari, A. N.; Carron, R. Efficiency boost of bifacial Cu(In,Ga)Se2 thin-film solar cells for flexible and tandem applications with silver-assisted low-temperature process. Nat. Energy 2023, 8, 40-51. https://doi.org/10.1038/s41560-022-01157-9
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Liang, H.; Feng, J.; Rodríguez-Gallegos, C. D.; Krause, M.; Wang, X.; Alvianto, E.; Guo, R.; Liu, H.; Kothandaraman, R. K.; Carron, R.; et al. 29.9%-efficient, commercially viable perovskite/CuInSe2 thin-film tandem solar cells. Joule 2023, 7 (12), 2859-2872. https://doi.org/10.1016/j.joule.2023.10.007
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Liu, S.; Becker, M.; Huang-Joos, Y.; Lai, H.; Homann, G.; Grissa, R.; Egorov, K.; Fu, F.; Battaglia, C.; Kühnel, R. S. Multifunctional additive ethoxy(pentafluoro)cyclotriphosphazene enables safe carbonate electrolyte for SiOx-graphite/NMC811 batteries. Batter. Supercaps 2023, 6 (7), e202300220 (10 pp.). https://doi.org/10.1002/batt.202300220
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Kopteva, N. E.; Yakovlev, D. R.; Kirstein, E.; Zhukov, E. A.; Kudlacik, D.; Kalitukha, I. V.; Sapega, V. F.; Hordiichuk, O.; Dirin, D. N.; Kovalenko, M. V.; et al. Weak dispersion of exciton Landé factor with band gap energy in lead halide perovskites: approximate compensation of the electron and hole dependences. Small 2023. https://doi.org/10.1002/smll.202300935
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Okur, F.; Zhang, H.; Karabay, D. T.; Muench, K.; Parrilli, A.; Neels, A.; Dachraoui, W.; Rossell, M. D.; Cancellieri, C.; Jeurgens, L. P. H.; et al. Intermediate-stage sintered LLZO scaffolds for Li-garnet solid-state batteries. Adv. Energy Mater. 2023, 13 (15), 2203509 (9 pp.). https://doi.org/10.1002/aenm.202203509
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Hallstrom, J.; Cherniukh, I.; Zha, X.; Kovalenko, M. V.; Travesset, A. Ligand effects in assembly of cubic and spherical nanocrystals: applications to packing of perovskite nanocubes. ACS Nano 2023, 17 (8), 7219-7228. https://doi.org/10.1021/acsnano.2c10079
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Anzini, P.; Biganzoli, D.; Cherniukh, I.; Kovalenko, M. V.; Parola, A.; Ferri, F. Variance analysis of dynamic light scattering data. Rev. Sci. Instrum. 2023, 94 (9), 095117 (11 pp.). https://doi.org/10.1063/5.0161845
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Grotevent, M. J.; Yakunin, S.; Bachmann, D.; Romero, C.; Vázquez de Aldana, J. R.; Madi, M.; Calame, M.; Kovalenko, M. V.; Shorubalko, I. Integrated photodetectors for compact Fourier-transform waveguide spectrometers. Nat. Photonics 2023, 17, 59-64. https://doi.org/10.1038/s41566-022-01088-7
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Montanarella, F.; Akkerman, Q. A.; Bonatz, D.; van der Sluijs, M. M.; van der Bok, J. C.; Prins, P. T.; Aebli, M.; Mews, A.; Vanmaekelbergh, D.; Kovalenko, M. V. Growth and self-assembly of CsPbBr3 nanocrystals in the TOPO/PbBr2 synthesis as seen with X-ray scattering. Nano Lett. 2023, 23 (2), 667-676. https://doi.org/10.1021/acs.nanolett.2c04532
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Boehme, S. C.; Bodnarchuk, M. I.; Burian, M.; Bertolotti, F.; Cherniukh, I.; Bernasconi, C.; Zhu, C.; Erni, R.; Amenitsch, H.; Naumenko, D.; et al. Strongly confined CsPbBr3 quantum dots as quantum emitters and building blocks for rhombic superlattices. ACS Nano 2023, 17 (3), 2089-2100. https://doi.org/10.1021/acsnano.2c07677
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Li, C.; Wang, X.; Bi, E.; Jiang, F.; Park, S. M.; Li, Y.; Chen, L.; Wang, Z.; Zeng, L.; Chen, H.; et al. Rational design of Lewis base molecules for stable and efficient inverted perovskite solar cells. Science 2023, 379 (6633), 690-694. https://doi.org/10.1126/science.ade3970
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Zhu, J.; Luo, Y.; He, R.; Chen, C.; Wang, Y.; Luo, J.; Yi, Z.; Thiesbrummel, J.; Wang, C.; Lang, F.; et al. A donor–acceptor-type hole-selective contact reducing non-radiative recombination losses in both subcells towards efficient all-perovskite tandems. Nat. Energy 2023, 8, 714-724. https://doi.org/10.1038/s41560-023-01274-z
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All Publications

All publications of the Group can be found in Digital Object Repository at Empa - DORA