Publications 2023

Kravchyk, K. V.; Kovalenko, M. V. On achievable gravimetric and volumetric energy densities of Al dual-ion batteries. ACS Energy Lett. 2023, 8 (2), 1266-1269. https://doi.org/10.1021/acsenergylett.2c02908
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Klimpel, M.; Zhang, H.; Kovalenko, M. V.; Kravchyk, K. V. Standardizing critical current density measurements in lithium garnets. Communications Chem. 2023, 6 (1), 192 (3 pp.). https://doi.org/10.1038/s42004-023-01002-4
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Montanarella, F.; Akkerman, Q. A.; Bonatz, D.; van der Sluijs, M. M.; van der Bok, J. C.; Prins, P. T.; Aebli, M.; Mews, A.; Vanmaekelbergh, D.; Kovalenko, M. V. Growth and self-assembly of CsPbBr3 nanocrystals in the TOPO/PbBr2 synthesis as seen with X-ray scattering. Nano Lett. 2023, 23 (2), 667-676. https://doi.org/10.1021/acs.nanolett.2c04532
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Anghel, S.; Poshakinskiy, A. V.; Yakovlev, D. R.; Kirstein, E.; Kopteva, N. E.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M.; Betz, M. Fast diffusion of spin polarized excitons in organic-inorganic lead halide perovskites. ACS Photonics 2023, 10, 4169-4176. https://doi.org/10.1021/acsphotonics.3c00891
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Strandell, D.; Dirin, D.; Zenatti, D.; Nagpal, P.; Ghosh, A.; Raino, G.; Kovalenko, M. V.; Kambhampati, P. Enhancing multiexcitonic emission in metal-halide perovskites by quantum confinement. ACS Nano 2023, 17 (24), 24910-24918. https://doi.org/10.1021/acsnano.3c06497
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Welty, C.; Taylor, E. E.; Posey, S.; Vailati, P.; Kravchyk, K. V.; Kovalenko, M. V.; Stadie, N. P. Methodological studies of the mechanism of anion insertion in nanometer-sized carbon micropores. ChemSusChem 2023, 16 (4), e202201847 (11 pp.). https://doi.org/10.1002/cssc.202201847
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Ren, A.; Wang, H.; Dai, L.; Xia, J.; Bai, X.; Butler-Caddle, E.; Smith, J. A.; Lai, H.; Ye, J.; Li, X.; et al. High-bandwidth perovskite photonic sources on silicon. Nat. Photonics 2023, 17, 798-805. https://doi.org/10.1038/s41566-023-01242-9
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Priebe, A.; Aribia, A.; Sastre, J.; Romanyuk, Y. E.; Michler, J. 3D high-resolution chemical characterization of sputtered Li-rich NMC811 thin films using TOF-SIMS. Anal. Chem. 2023, 95 (2), 1074-1084. https://doi.org/10.1021/acs.analchem.2c03780
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Boumenou, C. K.; Phirke, H.; Rommelfangen, J.; Audinot, J. N.; Nishiwaki, S.; Wirtz, T.; Carron, R.; Redinger, A. Nanoscale surface analysis reveals origins of enhanced interface passivation in RbF post deposition treated CIGSe solar cells. Adv. Funct. Mater. 2023, 33 (30), 2300590 (15 pp.). https://doi.org/10.1002/adfm.202300590
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Futscher, M. H.; Brinkman, L.; Müller, A.; Casella, J.; Aribia, A.; Romanyuk, Y. E. Monolithically-stacked thin-film solid-state batteries. Communications Chem. 2023, 6 (1), 110 (7 pp.). https://doi.org/10.1038/s42004-023-00901-w
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Siegrist, S.; Nandi, P.; Kothandaraman, R. K.; Abdessalem, A.; Tiwari, A. N.; Fu, F. Understanding coating thickness and uniformity of blade-coated SnO2 electron transport layer for scalable perovskite solar cells. Sol. RRL 2023, 7 (14), 2300273 (7 pp.). https://doi.org/10.1002/solr.202300273
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Shrivastava, M.; Krieg, F.; Kovalenko, M. V.; Adarsh, K. V. Photon-dressed biexciton-mediated anomalous optical Stark effect in CsPbBr3 nanocrystals. Surf. Interface Anal. 2023, 55 (6-7), 501-506. https://doi.org/10.1002/sia.7153
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Milanese, S.; Morello, G.; De Giorgi, M. L.; Cretì, A.; Andrusiv, H.; Bodnarchuk, M. I.; Qualtieri, A.; Lomascolo, M.; Kovalenko, M. V.; Anni, M. Air-sensitive amplified spontaneous emission in lecithin-capped CsPbBr3 nanocrystals thin films. Mater. Today Phys. 2023, 35, 101098 (8 pp.). https://doi.org/10.1016/j.mtphys.2023.101098
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Zhao, W.; Wang, K.; Dubey, R.; Ren, F.; Brack, E.; Becker, M.; Grissa, R.; Seidl, L.; Pagani, F.; Egorov, K.; et al. Extending the high-voltage operation of graphite/NCM811 cells by constructing a robust electrode/electrolyte interphase layer. Mater. Today Energy 2023, 34, 101301 (11 pp.). https://doi.org/10.1016/j.mtener.2023.101301
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Seiler, H.; Zahn, D.; Taylor, V. C. A.; Bodnarchuk, M. I.; Windsor, Y. W.; Kovalenko, M. V.; Ernstorfer, R. Direct observation of ultrafast lattice distortions during exciton-polaron formation in lead halide perovskite nanocrystals. ACS Nano 2023, 17 (3), 1979-1988. https://doi.org/10.1021/acsnano.2c06727
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Warby, J.; Shah, S.; Thiesbrummel, J.; Gutierrez-Partida, E.; Lai, H.; Alebachew, B.; Grischek, M.; Yang, F.; Lang, F.; Albrecht, S.; et al. Mismatch of quasi–fermi level splitting and Voc in perovskite solar cells. Adv. Energy Mater. 2023, 13 (48), 2303135 (12 pp.). https://doi.org/10.1002/aenm.202303135
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Tan, H. Q.; Liang, H.; Krause, M.; Zhao, X.; Kothandaraman, R.; Carron, R.; Tiwari, A. N.; Fu, F.; Birgersson, E.; Hou, Y.; et al. Accounting for fabrication variability in transparent perovskite solar cells for four-terminal tandem applications. Sol. RRL 2023, 7 (18), 2300339 (13 pp.). https://doi.org/10.1002/solr.202300339
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Nette, J.; Montanarella, F.; Zhu, C.; Sekh, T. V.; Boehme, S. C.; Bodnarchuk, M. I.; Rainò, G.; Howes, P. D.; Kovalenko, M. V.; deMello, A. J. Microfluidic synthesis of monodisperse and size-tunable CsPbBr3 supraparticles. Chem. Commun. 2023, 59, 3554 (4 pp.). https://doi.org/10.1039/d3cc00093a
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Dirin, D. N.; Vivani, A.; Zacharias, M.; Sekh, T. V.; Cherniukh, I.; Yakunin, S.; Bertolotti, F.; Aebli, M.; Schaller, R. D.; Wieczorek, A.; et al. Intrinsic formamidinium tin iodide nanocrystals by suppressing the Sn(IV) impurities. Nano Lett. 2023, 23, 1914-1923. https://doi.org/10.1021/acs.nanolett.2c04927
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Limantoro, C.; Das, T.; He, M.; Dirin, D.; Manos, J.; Kovalenko, M. V.; Chrzanowski, W. Synthesis of antimicrobial gallium nanoparticles using the hot injection method. ACS Mater. Au 2023, 3 (4), 310-320. https://doi.org/10.1021/acsmaterialsau.2c00078
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Carwithen, B. P.; Hopper, T. R.; Ge, Z.; Mondal, N.; Wang, T.; Mazlumian, R.; Zheng, X.; Krieg, F.; Montanarella, F.; Nedelcu, G.; et al. Confinement and exciton binding energy effects on hot carrier cooling in lead halide perovskite nanomaterials. ACS Nano 2023, 17 (7), 6638-6648. https://doi.org/10.1021/acsnano.2c12373
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Müller, A.; Okur, F.; Aribia, A.; Osenciat, N.; Vaz, C. A. F.; Siller, V.; El Kazzi, M.; Gilshtein, E.; Futscher, M. H.; Kravchyk, K. V.; et al. Benchmarking the performance of lithiated metal oxide interlayers at the LiCoO2|LLZO interface. Mater. Adv. 2023, 4 (9), 2138-2146. https://doi.org/10.1039/d3ma00155e
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Bertolotti, F.; Dengo, N.; Cervellino, A.; Bodnarchuk, M. I.; Bernasconi, C.; Cherniukh, I.; Berezovska, Y.; Boehme, S. C.; Kovalenko, M. V.; Masciocchi, N.; et al. Size- and temperature-dependent lattice anisotropy and structural distortion in CsPbBr3 quantum dots by reciprocal space X-ray total scattering analysis. Small Struct. 2023. https://doi.org/10.1002/sstr.202300264
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Kurisinkal Pious, J.; Zwirner, Y.; Lai, H.; Olthof, S.; Jeangros, Q.; Gilshtein, E.; Kothandaraman, R. K.; Artuk, K.; Wechsler, P.; Chen, C.; et al. Revealing the role of tin fluoride additive in narrow bandgap Pb-Sn perovskites for highly efficient flexible all-perovskite tandem cells. ACS Appl. Mater. Interfaces 2023, 15 (7), 10151-10157. https://doi.org/10.1021/acsami.2c19124
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Tonkaev, P.; Grechaninova, E.; Iorsh, I.; Montanarella, F.; Kivshar, Y.; Kovalenko, M. V.; Makarov, S. Multiscale supercrystal meta-atoms. Nano Lett. 2023, 24, 2758-2764. https://doi.org/10.1021/acs.nanolett.3c04580
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Zhang, Z.; Huang, Y.; Wang, C.; Jiang, Y.; Jin, J.; Xu, J.; Li, Z.; Su, Z.; Zhou, Q.; Zhu, J.; et al. Green-antisolvent-regulated distribution of p-type self-doping enables tin perovskite solar cells with an efficiency of over 14%. Energy Environ. Sci. 2023, 16 (8), 3430-3440. https://doi.org/10.1039/d3ee00601h
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Liu, S.; Becker, M.; Huang-Joos, Y.; Lai, H.; Homann, G.; Grissa, R.; Egorov, K.; Fu, F.; Battaglia, C.; Kühnel, R. S. Multifunctional additive ethoxy(pentafluoro)cyclotriphosphazene enables safe carbonate electrolyte for SiOx-graphite/NMC811 batteries. Batter. Supercaps 2023, 6 (7), e202300220 (10 pp.). https://doi.org/10.1002/batt.202300220
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Grisard, S.; Trifonov, A. V.; Solovev, I. A.; Yakovlev, D. R.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M.; Akimov, I. A. Long-lived exciton coherence in mixed-halide perovskite crystals. Nano Lett. 2023, 23 (16), 7397-7403. https://doi.org/10.1021/acs.nanolett.3c01817
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Häusermann, D.; Bodry, S.; Wiesemüller, F.; Miriyev, A.; Siegrist, S.; Fu, F.; Gaan, S.; Koebel, M. M.; Malfait, W. J.; Zhao, S.; et al. FireDrone: multi-environment thermally agnostic aerial robot. Adv. Intell. Syst. 2023, 5 (9), 2300101 (11 pp.). https://doi.org/10.1002/aisy.202300101
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He, R.; Wang, W.; Yi, Z.; Lang, F.; Chen, C.; Luo, J.; Zhu, J.; Thiesbrummel, J.; Shah, S.; Wei, K.; et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 2023, 618 (7963), 80-86. https://doi.org/10.1038/s41586-023-05992-y
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Yang, S. C.; Lin, T. Y.; Ochoa, M.; Lai, H.; Kothandaraman, R.; Fu, F.; Tiwari, A. N.; Carron, R. Efficiency boost of bifacial Cu(In,Ga)Se2 thin-film solar cells for flexible and tandem applications with silver-assisted low-temperature process. Nat. Energy 2023, 8, 40-51. https://doi.org/10.1038/s41560-022-01157-9
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Baumgärtner, J. F.; Wörle, M.; Guntlin, C. P.; Krumeich, F.; Siegrist, S.; Vogt, V.; Stoian, D. C.; Chernyshov, D.; van Beek, W.; Kravchyk, K. V.; et al. Pyrochlore‐type iron hydroxy fluorides as low‐cost lithium‐ion cathode materials for stationary energy storage. Adv. Mater. 2023, 35 (49), 2304158 (11 pp.). https://doi.org/10.1002/adma.202304158
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Moser, S.; Tiwari, A. N.; Carron, R. Interplay between Li and Na amid co-doped solution-processed Cu2ZnSn(S,Se)4 absorbers for solar cells. Sol. Energy Mater. Sol. Cells 2023, 250, 112094 (9 pp.). https://doi.org/10.1016/j.solmat.2022.112094
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Moser, S.; Aribia, A.; Scaffidi, R.; Gilshtein, E.; Brammertz, G.; Vermang, B.; Tiwari, A. N.; Carron, R. Controlled li alloying by postsynthesis electrochemical treatment of Cu2ZnSn(S, Se)4 absorbers for solar cells. ACS Appl. Energy Mater. 2023, 6 (24), 12515-12525. https://doi.org/10.1021/acsaem.3c02483
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Kara, G.; Bolat, S.; Sharma, K.; Grotevent, M. J.; Dirin, D. N.; Bachmann, D.; Furrer, R.; Boesel, L. F.; Romanyuk, Y. E.; Rossi, R. M.; et al. Conformal integration of an inkjet‐printed PbS QDs‐graphene IR photodetector on a polymer optical fiber. Adv. Mater. Technol. 2023, 8 (9), 2201922 (11 pp.). https://doi.org/10.1002/admt.202201922
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Grotevent, M. J.; Yakunin, S.; Bachmann, D.; Romero, C.; Vázquez de Aldana, J. R.; Madi, M.; Calame, M.; Kovalenko, M. V.; Shorubalko, I. Integrated photodetectors for compact Fourier-transform waveguide spectrometers. Nat. Photonics 2023, 17, 59-64. https://doi.org/10.1038/s41566-022-01088-7
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Kopteva, N. E.; Yakovlev, D. R.; Kirstein, E.; Zhukov, E. A.; Kudlacik, D.; Kalitukha, I. V.; Sapega, V. F.; Hordiichuk, O.; Dirin, D. N.; Kovalenko, M. V.; et al. Weak dispersion of exciton Landé factor with band gap energy in lead halide perovskites: approximate compensation of the electron and hole dependences. Small 2023. https://doi.org/10.1002/smll.202300935
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Harkort, C.; Kudlacik, D.; Kopteva, N. E.; Yakovlev, D. R.; Karzel, M.; Kirstein, E.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. Spin-flip raman scattering on electrons and holes in two-dimensional (PEA)2PbI4 perovskites. Small 2023, 19 (32), 2300988 (10 pp.). https://doi.org/10.1002/smll.202300988
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Bojar, A.; Micha, D.; Giteau, M.; Ruiz-Preciado, M. A.; Paetzold, U. W.; Simor, M.; Gevaerts, V. S.; Carron, R.; Medjoubi, K.; Collin, S.; et al. Optical simulations and optimization of perovskite/CI(G)S tandem solar cells using the transfer matrix method. J. Phys. Energy 2023, 5 (3), 035001 (12 pp.). https://doi.org/10.1088/2515-7655/accf34
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Luo, J.; He, R.; Lai, H.; Chen, C.; Zhu, J.; Xu, Y.; Yao, F.; Ma, T.; Luo, Y.; Yi, Z.; et al. Improved carrier management via a multifunctional modifier for high-quality low-bandgap Sn–Pb perovskites and rfficient sll-perovskite tandem solar cells. Adv. Mater. 2023, 35 (22), 2300352 (11 pp.). https://doi.org/10.1002/adma.202300352
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Sakhatskyi, K.; Turedi, B.; Matt, G. J.; Wu, E.; Sakhatska, A.; Bartosh, V.; Lintangpradipto, M. N.; Naphade, R.; Shorubalko, I.; Mohammed, O. F.; et al. Stable perovskite single-crystal X-ray imaging detectors with single-photon sensitivity. Nat. Photonics 2023, 17, 510-517. https://doi.org/10.1038/s41566-023-01207-y
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Zhang, H.; Paggiaro, G.; Okur, F.; Huwiler, J.; Cancellieri, C.; Jeurgens, L. P. H.; Chernyshov, D.; Van Beek, W.; Kovalenko, M. V.; Kravchyk, K. V. On high-temperature thermal cleaning of Li7La3Zr2O12 solid-state electrolytes. ACS Appl. Energy Mater. 2023, 6 (13), 6972-6980. https://doi.org/10.1021/acsaem.3c00459
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Zhang, H.; Dubey, R.; Inniger, M.; Okur, F.; Wullich, R.; Parrilli, A.; Karabay, D. T.; Neels, A.; Kravchyk, K. V.; Kovalenko, M. V. Ultrafast-sintered self-standing LLZO membranes for high energy density lithium-garnet solid-state batteries. Cell Rep. Phys. Sci. 2023, 4 (7), 101473 (15 pp.). https://doi.org/10.1016/j.xcrp.2023.101473
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Zhu, J.; Luo, Y.; He, R.; Chen, C.; Wang, Y.; Luo, J.; Yi, Z.; Thiesbrummel, J.; Wang, C.; Lang, F.; et al. A donor–acceptor-type hole-selective contact reducing non-radiative recombination losses in both subcells towards efficient all-perovskite tandems. Nat. Energy 2023, 8, 714-724. https://doi.org/10.1038/s41560-023-01274-z
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Okur, F.; Zhang, H.; Karabay, D. T.; Muench, K.; Parrilli, A.; Neels, A.; Dachraoui, W.; Rossell, M. D.; Cancellieri, C.; Jeurgens, L. P. H.; et al. Intermediate-stage sintered LLZO scaffolds for Li-garnet solid-state batteries. Adv. Energy Mater. 2023, 13 (15), 2203509 (9 pp.). https://doi.org/10.1002/aenm.202203509
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Kumaar, D.; Can, M.; Portner, K.; Weigand, H.; Yarema, O.; Wintersteller, S.; Schenk, F.; Boskovic, D.; Pharizat, N.; Meinert, R.; et al. Colloidal ternary telluride quantum dots for tunable phase change optics in the visible and near-infrared. ACS Nano 2023, 17 (7), 6985-6997. https://doi.org/10.1021/acsnano.3c01187
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Hallstrom, J.; Cherniukh, I.; Zha, X.; Kovalenko, M. V.; Travesset, A. Ligand effects in assembly of cubic and spherical nanocrystals: applications to packing of perovskite nanocubes. ACS Nano 2023, 17 (8), 7219-7228. https://doi.org/10.1021/acsnano.2c10079
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Kirstein, E.; Smirnov, D. S.; Zhukov, E. A.; Yakovlev, D. R.; Kopteva, N. E.; Dirin, D. N.; Hordiichuk, O.; Kovalenko, M. V.; Bayer, M. The squeezed dark nuclear spin state in lead halide perovskites. Nat. Commun. 2023, 14 (1), 6683 (8 pp.). https://doi.org/10.1038/s41467-023-42265-8
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Yakovlev, D. R.; Crooker, S. A.; Semina, M. A.; Rautert, J.; Mund, J.; Dirin, D. N.; Kovalenko, M. V.; Bayer, M. Exciton‐polaritons in CsPbBr3 crystals revealed by optical reflectivity in high magnetic fields and two‐photon spectroscopy. Phys. Status Solidi Rapid Res. Lett. 2023 (19 pp.). https://doi.org/10.1002/pssr.202300407
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Tamarat, P.; Prin, E.; Berezovska, Y.; Moskalenko, A.; Nguyen, T. P. T.; Xia, C.; Hou, L.; Trebbia, J. B.; Zacharias, M.; Pedesseau, L.; et al. Universal scaling laws for charge-carrier interactions with quantum confinement in lead-halide perovskites. Nat. Commun. 2023, 14, 229 (8 pp.). https://doi.org/10.1038/s41467-023-35842-4
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All Publications

All publications of the Group can be found in Digital Object Repository at Empa - DORA